Chemical elements
  Silicon
    Isotopes
    Energy
    Physical Properties
    Chemical Properties
      Silicon Tetrahydride
      Silicomethane
      Silicane
      Silico-ethane
      Silico-acetylene
      Bromosilicane
      Silicofluoroform
      Trifluorosilicane
      Silicochloroform
      Trichlorosilicane
      Silicobromoform
      Tribromosilicane
      Silico-iodoform
      Tri-iodosilicane
      Silicon Tetrafluoride
      Hydrofluosilicic Acid
      Silicon Subfluoride
      Silicon Tetrachloride
      Tetrachlorosilicane
      Silicon Tetrabromide
      Tetrabromosilicane
      Silicon Tetra-iodide
      Tetra-iodosilicane
      Mixed Halides of Silicon
      Halogen Derivatives of Silico-ethane
      Halogen Derivatives of Silicopropane
      Halogen Derivatives of Silicobutane
      Halogen Derivatives of Silicopentane and Silicohexane
      Silicon Oxychlorides
      Silica
      Silicon Dioxide
      Silicates
      Silicoformic Anhydride
      Silico-oxalic Acid
      Silicomes-oxalic Acid
      Silicon Disulphide
      Silicon Monosulphide
      Silicon Oxysulphide
      Silicon Thiochloride
      Silicon Thiobromide
      Silicon Chloroitydrosulphide
      Silicothio-urea
      Silicon Selenide
      Silicon Tetramide
      Silicon Di-imide
      Silicon Nitrimide
      Silicam
      Siliconitrogen Hydride
      Silicon Nitrides
      Crystalline Silicon Monocarbide
      Carborundum
      Silicon Dicarbide
      Silicon Carboxide
      Borides of Silicon
    PDB 1fuq-4ehr

Crystalline Silicon Monocarbide, SiC






The discovery of Crystalline Silicon Monocarbide (Carborundum), SiC, by Acheson in 1891 was an outcome of the experiments of Moissan on the electric furnace. It may be prepared by fusing silicon with carbon, or silica with calcium carbide, in an electric furnace, or by the combination of carbon and silicon vapours produced therein. It is manufactured, however, by heating together in an electric furnace, built of firebrick and provided with carbon terminals, a mixture of coke, silica, salt, and sawdust. The water-power of Niagara furnishes the energy. The reactions are:

SiO2 + 2C = Si + 2CO; Si + C = SiC.

The salt acts as a flux till it is volatilised, and the sawdust yields gaseous decomposition products which keep the mass porous. When the furnace is opened the carborundum is found surrounded with a zone of the less valuable amorphous monocarbide, formed at a lower temperature.

Carborundum crystallises in hexagonal plates of density 3.12. The crystals are lustrous, iridescent, and often translucent, and of a colour varying from sapphire blue to greenish brown. The hardness of this substance approaches that of diamond, being 9.5 on Moh's scale; so that it will scratch ruby. The heats of formation and combustion are respectively

Si (cryst.) + C (amorph.) = SiC + 2000 calories
SiC + 2O2 = SiO2 + CO2 + 238,800 calories.

Carborundum is practically unaltered by ignition at 1000° C. in air or oxygen. Neither hydrochloric nor sulphuric acid, nor even a mixture of hydrofluoric and nitric acids, attacks this substance; sulphur and fused nitre are without action upon it; chlorine decomposes it, slightly at 600° C., completely at 1200° C.; fused lead chromate oxidises it, and fused caustic alkali converts it into carbonate and silicate. Carborundum is used, on account of its excessive hardness, as an abrading, cutting, and polishing agent. It is employed in the iron and steel and other metal industries, and for smoothing pottery and polishing granite and glass. It is thus a substitute for emery.


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